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OBJECTIONABLE LIMITS OF VARIOUS SUBSTANCES AND THEIR
RELATION TO PRACTICAL PROBLEMS
Prior to about 1890 attempt was made to judge the sanitary quality of water chiefly on its chemical analysis with more or less consideration to conditions at the source. With the development of bacteriological methods, however, the chemical analyses, except for comparative purposes, have received less and less attention. The chemical composition of water is subject to the effects of so many varying factors which have no sanitary significance whatever, that it is difficult, without making an extensive series of tests at fairly frequent intervals, to say what is the normal chemical content for water from a given region.
The substances determined and reported in the sanitary chemical water analyses are of themselves harmless even in high concentrations. Since it was recognized long before the development
. of modern bacteriology that the pollution of water with human excreta was one of the most menacing sources of disease, chemists attempted to devise tests by which it would be possible to detect such pollution. A brief description of the substances determined in the sanitary chemical analysis and their significance are given below.
The "oxygen consumed” test is a measure of the oxidizable matter contained in water and indicates the presence of certain forms of organic material or other oxidizable substances. The test serves to compare the relative amounts of carbonaceous organic matter or other oxidizable constituents in samples of water from various sources.
Since fecal matter is known to be composed of that class of biological substance known as protein and characteristically to contain nitrogen, the sanitary chemical water analysis includes the determination of four different forms of nitrogen-as albuminoid ammonia (or Kjeldahl nitrogen), as free ammonia, as nitrites and as nitrates. The relative amount of these substances found in water indicates in a comparative way the quality of the samples analyzed. The former indicate crude organic matter, nitrates, completely mineralized matter; and free ammonia and nitrites, intermediate steps in the cycle of nitrogen changes.
Albuminoid nitrogen includes the nitrogen which is still a part of the protein-like organic substance. It is the nitrogenous organic matter of either animal or vegetable origin in an undecomposed condition. Free ammonia nitrogen is nitrogen which has undergone the first stages of mineralization; that is, it is no longer combined with organic substances.
The next step in mineralization produces nitrite. Since nitrites are rather unstable, they are not ordinarily found except where an active chemical change is going on. This form of nitrogen is in fact the transitional stage of the conversion of the complex organic nitrogen into the fully mineralized form.
Nitrates represent the final stage of oxidation of nitrogen in the completely mineralized form. The nitrate content of a water indicates somewhat its past history, and serves as an index of the so-called "remote pollution.” Nitrates in ground water or from deep sources are frequently excessive due to mineral deposits and under these conditions have no sanitary significance.
Chlorides are a measure of the chloride salts of which sodium chloride, ordinary table salt, is by far the major constituent. This substance is perfectly harmless in itself, but since sewage contains relatively large amounts of salt, pollution may be detected by the abnormally high chloride content of a water. Interpretation of the sanitary significance of chlorides in water depends, therefore, upon local conditions and the quantity of chloride present in the sample. In sections where the normal chloride content of the water is high, due to saline deposits in the ground or to industrial wastes, the chloride content as a sanitary factor is to be excluded or discounted.
The turbidity is a measure of the physical condition of the water indicating the presence of suspended solids of an organic or inorganic nature. Waters containing a large amount of turbidity are unsuitable for domestic use and for many industrial processes.
The total solids represent the total amount of matter carried by the water, as determined by evaporation. There is no definite limit as to the amount of solids that may be present in the water which determines its potability.
The alkalinity of water is a measure of the salts that neutralize acids. These may be present in a number of different forms, but the ones generally encountered in waters are carbonates, bi-carbonates and hydrates. Except under unusual conditions, the alkalinity of a water has no sanitary significance.
SUBSTANCES IN NATURAL WATERS
GYPSUM, PLASTER OF PARIS
IRON RUST 'SiO2
Silica - sand, etc.
The hardness of water is a measure of its soap consuming power. This phenomenon is caused by the presence of certain soluble constituents in the water, of which calcium and magnesium are the most important.
Elsewhere in this volume reference is made in more or less detail to limiting quantities for other chemical constituents of water. The reader is referred particularly to the sections on chlorination, for limiting values of free chlorine for taste avoidance; on corrosion, for carbon dioxide limits; on self-purification of streams, for dissolved oxygen depletion figures in relation to stagnation; on removal of iron and manganese, for prevention of stains from iron salts; and on quality of water, for limitations in lead content for prevention of lead-poisoning or plumbism.
STANDARDS OF WATER SUPPLY QUALITY
The quality of a water is a variable attribute, intricately dependent upon a series of mutual physical, chemical and biological phenomena. Its measurement, therefore, is difficult and cannot be adequately carried out by the evaluation of only one of its characteristics. The real consideration or interpretation of the potability of a supply involves a series of mutually active attributes, each of which plays a part of importance in modifying and determining the character of the water. The single ultimate unit of measure or the final standard becomes, in this way, an index number of properly weighted individual and fundamental units.
In order to avoid repetition of detailed discussion on this question, two standards of water supply quality are here reproduced to illustrate the application of limiting values to the above units under conditions practically ten years apart. In 1914 the Public Health Service of the United States Treasury Department promulgated a standard of water supply quality for water used on interstate carriers. Its application was to be restricted to the water as used on the carriers. In practice, however, it came to be applied to all municipal water supplies, with attendant disadvantages, since the 1914 standard was concerned with only bacterial content of the water sample on a railroad car. The concepts of quality outlined above were ignored therein, because of the specialized use to which the standard was to be put.
When it was realized that the consideration of the quality of water on trains could not easily be separated from that of the municipal supply from which it was obtained, it became necessary to review the quality of the supply by reference to its history or origin, treatment and resulting condition, physical, chemical and bacterial. This realization has resulted in the development of a new standard of water supply quality, still applicable in theory only to waters on interstate carriers, but practically adaptable to municipal water supply conditions. This new standard, more complex than that issued in 1914, and, therefore, more in keeping with the complexity of the problem involved, was issued by the United States Public Health Service in 1925. It is reproduced here in full, since its principles are accepted by the water works profession. Whether the limiting values involved in the quantitative statements of those principles are generally acceptable is not nearly so important, for these are adjustable to variable needs and conditions. The 1925 report states with brevity the essential principles involved in the evaluation of water supply quality. As such its importance in this text is clear.
1914-BACTERIOLOGICAL STANDARD FOR DRINKING WATER Pursuant to the recommendation of the Surgeon General, the Treasury Department on October 21, 1914, adopted a bacteriological standard for drinking water for the purpose of the administration of the Interstate Quarantine Regulations as they relate to the drinking water supplied to the public by common carriers in interstate commerce.
The bacteriological standard for water The following are the maximum limits of permissible bacteriogical impurity:
1. The total number of bacteria developing on standard agar plates, incubated twenty-four hours at 37°C., shall not exceed 100 per cubic centimeter. Provided, that the estimate shall be made from not less than two plates, showing such numbers and distribution of colonies as to indicate that the estimate is reliable and accurate.
2. Not more than one out of five 10 cc. portions of any sample examined shall show the presence of organisms of the bacillus coli group when tested as follows:
a. Five 10 cc. portions of each sample tested shall be planted,
1 The Standard adopted by the Treasury Department for Drinking Water Supplied to the Public by Common Carriers in Interstate Commerce. Reprint from the Public Health Reports, vol. 29, no. 45, November 6, 1914.